Product ID:83295 SHELL SOL B HT
MSDS Date:10/28/1993
FSC:6850
NIIN:00F025209
MSDS Number: BNZKG

SHELL OIL CO

1 SHELL PLZ
HOUSTON, TX 77001
US

Emergency Phone: (713) 473-9461

Info Phone: (713) 241-4819

Preparer: J. C. WILLETT

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE

CAS: 64742-89-8

Fraction By Weight: <100%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

HEXANE, N-HEXANE

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <25-35%

OSHA PEL 1800 MG/CUM

ACGIH TLV: 176 MG/CUM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

CYCLOHEXANE

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: 1-2%

OSHA PEL 1050 MG/CUM

ACGIH TLV: 1030 MG/CUM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-METHYL PENTANE, ISOHEXANE

CAS: 107-83-5

RTECS: SA2995000

Fraction By Weight: 20-24%

ACGIH TLV: 500 PPM

3-METHYL PENTANE

CAS: 96-14-0

RTECS: SA2995500

Fraction By Weight: 18-23%

LD50 LC50 Mixture:ORAL LD50 (RAT): >25 ML/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION,
DERMATITIS. INHALATION: MAY CAUSE IRRITATION TO THE NOSE, THROAT &
RESPIRATORY TRACT, CNS DEPRESSION. N-HEXANE: MAY PRODUCE PERIPHERAL
& CENTRAL NERVE DAMAGE. INGES TION: ASPIRATION OF VOMITUS INTO THE
LUNGS MAY RESULT IN ASPIRATION PNEUMONITIS. DEATH MAY OCCUR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DEFATTTING/DRYING OF THE SKIN,
VOMITING, GIDDINESS, HEADACHE, DIZZINESS, NAUSEA, UNCONSCIOUSNESS,
COUGHING, LABORED BREATHING, CYANOSIS, MUSCULAR WEAKNESS, LOSS OF
SENSATION IN THE ARMS & LEGS
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, RESPIRATORY
DISORDERS. IMPAIRED PERIPHERAL NERVE FUNCTIONS.

First Aid:EYES: FLUSH W/WATER. SKIN: FLUSH W/WATER & WASH W/SOAP &
WATER. INHALATION: REMOVE TO FRESH AIR/PROVIDE OXYGEN/CPR IF
NECESSARY. INGESTION: DON'T INDUCE VOMITING. IF VOMITING OCCURS
SPONTANEOUSLY. KEE P HEAD LUNGS. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN:
EMESIS SHOULD BE INDUCED W/SUPERVISION. IF UNCONSCIOUS, GASTRIC
LAVAGE SHOULD BE CONSIDERED

Flash Point Method:TCC
Flash Point:0F
Lower Limits:1
Upper Limits:7
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL/CO2
Fire Fighting Procedures:EVACUATE PERSONNEL, ISOLATE AREA. DON'T ENTER
CONFINED SPACE W/O FULL BUNKER GEAR & POSITIVE PRESSURE NIOSH
APPROVED SCBA. COOL FIRE EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT MAY
CAUSE VAPOR PRESSURE BUILDUP & RESULT IN CONTAINER RUPTURE. DIRECT
FLAME MAY CAUSE WEAKENING OF CONTAINER STRUCTURE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. LARGE-ISOLATE AREA
& DENY ENTRY. WEAR RESPIRATOR & PROTECTIVE CLOTHING. SHUT OFF
SOURCE OF LEAK SAFELY. DIKE/CONTAIN. WATER FOG MAY BE USEFUL.
CONTAIN RUN-OFF. REMOVE W/VAC UUM TRUCKS/PUMP TO STORAGE/SALVAGE
VESSELS. (SUPP)

Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. USE ADEQUATE VENTILATION. CONTAINERS THAT HAVE BEEN EMPTIED
CAN CONTAIN EXPLOSIVE VAPORS.
Other Precautions:DON'T CUT, DRILL, GRIND, WELD ON/NEAR CONTAINERS.
DON'T PRESSURIZE DRUM CONTAINERS TO EMPTY THEM. GROUND FIXED
EQUIPMENT. BOND & GROUND TRANSFER CONTAINERS & EQUIPMENT. AVOID
PROLONGED/REPEATED BREATH ING OF VAPORS & CONTACT W/SKIN & EYES.

Respiratory Protection:IF EXPOSURE >OCCUPATIONAL EXPOSURE USE A NIOSH
APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. USE ATMOSPHERE
SUPPLYING RESPIRATOR OR AN AIR PURIFYING RESPIRATOR FOR ORGANIC
VAPORS.
Ventilation:EXPLOSION-PROOF VENTILATION TO CONTROL VAPOR
CONCENTRATIONS.
Protective Gloves:CHEMICAL RESISTANT
Eye Protection:SAFETY GLASSES/GOGGLES
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES.
AIR-DRY CONTAMINATED CLOTHING IN A WELL VENTILATED AREA BEFORE
LAUNDERING.
Supplemental Safety and Health
SPILL PROC CON'D: SOAK UP RESIDUE W/ABSORBENT. PLACE IN NON-LEAKING
CONTAINERS FOR PROPER DISPOSAL. FLUSH AREA W/WATER. DISPOSE OF
FLUSH SOLUTIONS. SMALL: SAME AS ABOVE. VAPORS MAY ACCUMULATE &
TRAVEL TO IGNITION SOURCES DISTANT FROM HANDLING SITE; FLASH FIRE
CAN RESULT.

Boiling Pt:B.P. Text:142-183F
Vapor Pres:320
Vapor Density:2.9
Spec Gravity:0.674
Evaporation Rate & Reference:(N-BU-AC = 1): 9.1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID W/HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, FLAME, HOT SURFACES, STATIC
ELECTRICITY & OTHER IGNITION SOURCES, VAPOR ACCUMMULATION
Hazardous Decomposition Products:CO & UNIDENTIFIED ORGANIC COMPOUNDS

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. PLACE IN NON-LEAKING CONTAINER FOR PROPER
DISPOSAL. FLAMMABLE LIQUIDS UN1268.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.